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Oxygen Coordination to the Active Site of Hmd in Relation to [FeFe] Hydrogenase

โœ Scribed by Martin T. Stiebritz; Arndt R. Finkelmann; Markus Reiher


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
652 KB
Volume
2011
Category
Article
ISSN
1434-1948

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โœ Kรฉvin Charreteur; Jean-Franรงois Capon; Frรฉdรฉric Gloaguen; Franรงois Y. Pรฉtillon; ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 317 KB ๐Ÿ‘ 1 views

## Abstract Sixโ€membered heterocycles, 1,4โ€dithiane and 1,4โ€thioxane, were treated with [Fe~2~(CO)~6~(ฮผโ€pdt)] (pdt = propanedithiolate) in order to synthesise [2Fe3S] complexes with well positioned heteroatoms as potential base. Monosubstituted compounds of general formula [Fe~2~(CO)~5~L(ฮผโ€pdt)] (L