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Phosphane and Phosphite Unsymmetrically Disubstituted Diiron Complexes Related to the Fe-Only Hydrogenase Active Site

✍ Scribed by Ping Li; Mei Wang; Chengjiang He; Xiaoyang Liu; Kun Jin; Licheng Sun

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
315 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Influence of a Redox-Active Phosphane Li
Influence of a Redox-Active Phosphane Ligand on the Oxidations of a Diiron Core Related to the Active Site of Fe-Only Hydrogenase
✍ Yu-Chiao Liu; Chia-Hsin Lee; Gene-Hsiang Lee; Ming-Hsi Chiang πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 725 KB

## Abstract Modulation of the Fe redox levels within the diiron dithiolato carbonyls with the coordination of a redox‐active phosphane is reported. Treatment of [Fe~2~{μ‐S(CH~2~)~2~NR(CH~2~)~2~S}(CO)~6~]~2~ and [Fe~2~(μ‐pdt)(CO)~6~] with mppf affords the phosphane substituted species, [Fe~2~{μ‐S(CH