An Oxidized Active Site Model for the FeFe Hydrogenase: Reduction with Hydrogen Gas
β Scribed by Matthews, Steven L.; Heinekey, D. Michael
- Book ID
- 126463339
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 1023 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0020-1669
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## Abstract A short overview of diiron dichalcogenolato (Se and Te) model complexes related to the chemistry of the diiron subsite of [FeFe] hydrogenase is presented. These model complexes allow direct comparison with the diiron dithiolato compound analogues for their ability to catalyze the format
## Abstract The oxidation of the hexacarbonyl(1,3βdithiolatoβ__S__,__S__β²)diiron complexes **4a**β**4c** with varying amounts of dimethyldioxirane (DMD) was systematically studied. The chemoselectivity of the oxidation products depended upon the substituent R (R=H, Me, 1/2 (CH~2~)~5~). For R=H, fou