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Efficient synthesis of substituted oxopiperazines from amino acids

โœ Scribed by Nazim Mohamed; Ulhas Bhatt; George Just

Book ID
104260111
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
168 KB
Volume
39
Category
Article
ISSN
0040-4039

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Two routes for the synthesis of derivatized oxopiperazines, which may act as constrained peptide mimics, are reported The syntheses employ reductive amination and sulfonamide approaches for generating N-allylic amino acid ester derivatives and utilizing them for assembling the ring systems. An aspar

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Derivatized Oxopiperazine Rings from Amino Acids. -Two dipeptide mimics (VII) and (XIV) are synthesized by employment of reductive amination and sulfonamide approaches for the preparation of allylic derivatives (IV) and (XIII), which are further utilized for assembling the ring systems, as is shown