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Efficient Routes to Chiral 2-Substituted and 2,6-Disubstituted Piperidines

✍ Scribed by Katritzky, Alan R.; Qiu, Guofang; Yang, Baozhen; Steel, Peter J.

Book ID
120802240
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
154 KB
Volume
63
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

An enantioselective route to trans-2,6-d
An enantioselective route to trans-2,6-disubstituted piperidines
✍ Samuel Chackalamannil; Yuguang Wang πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 390 KB

The synthesis of (S)-2-methyl tetrahydropyridine-N-oxide (4), a key intermediate for the enantioselective construction of trans-2,6-disubsdtuted piperidines via [3+2] nitrone cycloaddition reaction, is described. Nitrone 4 was elaborated to the fire ant venom alkaloid (+)-solenopsin-A (2) via interm