Efficient Route to Tetramethylalumoxane and Carboxylate Alumoxanes through the Alkylation of Phthalic Acid
✍ Scribed by Janusz Lewiński; Wojciech Bury; Iwona Justyniak; Janusz Lipkowski
- Book ID
- 101535305
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 311 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Radical addition to a glyoxylic oxime ether was accomplished under mild conditions using an alkyl radical generated from a free carboxylic acid via photochemical decarboxylation. The photoreaction provided an efficient route to a-substituted a-aminoesters from carboxylic acids and oxime ether.
Carboxylic acids were conveniently esterfied with alcohols and thiols by the use of triphenylphosphine and N-bromo/Iodo succinimide to afford the corresponding esters and thiol esters. Conversion of carboxylic acids to their corresponding esters and thiol esters is a well established fundamental org