Efficient Resolution of (.+-.)-1-(9-Anthryl)ethylamine.
β Scribed by Marin Roje; Zdenko Hamersak; Vitomir Sunjic
- Book ID
- 101935939
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 60 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
## Abstract Racemic 1β(9βanthryl)ethylamine (**10**), obtained in 70% overall yield from commercial 9βcyanoanthracene, was kinetically resolved by the __Candida antarctica A__ lipaseβcatalyzed acetylation with isopropyl acetate as acyl donor, affording (__R__)β(+)β**10** with 95.8% enantiomeric exc
Enantioselective reduction of prochiral 9-anthryl ketones to the corresponding chiral alcohols proceeds with high enantiomeric excess. The chiral alcohol 1-(9-anthryl)-2-bromo-ethanol can be converted to the corresponding chiral oxirane. (~