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Efficient Regio- and Stereoselective Synthesis of 1-β-O-Glucuronyl Carbamates and Carbonates from Unprotected 1,2,3,4-Hydroxyl Glucuronates.

✍ Scribed by Mickael Thomas; Jean-Pierre Gesson; Sebastien Papot

Publisher: John Wiley and Sons
Year: 2007
Weight: 28 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200750198

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✦ Synopsis

Abstract

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## Abstract An efficient protocol for the highly regio‐ and stereoselective synthesis of 4‐(3′‐hydroxy‐2′‐iodoalk‐1′(__Z__)‐enyl)furan‐2(5__H__)‐one derivatives __via__ selective iodohydroxylation of non‐heteroatom‐substituted allenes, i.e., 4‐allenyl‐2(5__H__)furanones, has been developed. The reg