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Efficient preparation of allylic grignard reagents using slurries of precondensed magnesium

✍ Scribed by Wolfgang Oppolzer; Ernest Peter Kündig; Paul M. Bishop; Celia Perret

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 219 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87738-2

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✦ Synopsis

Using a simple apparatus addltlon of 2-alkenyl halldes to precondensed active Mg In THF gave clean solutions of 2-alkenylmagneslum halldes which on carbonation furnished 8,y-unsaturated carboxyllc acids In high yields.

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