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Efficient One-Pot Synthesis of Secondary Cyclic Phosphanes with Easy Regeneration of the Phosphorus-Donor Reagent Used

✍ Scribed by Graziano Baccolini; Carla Boga; Matteo Galeotti


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
94 KB
Volume
43
Category
Article
ISSN
0044-8249

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General and Efficient One-Pot Synthesis
✍ Graziano Baccolini; Carla Boga; Marzia Mazzacurati 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB

## Abstract Tertiary symmetric and asymmetric phosphane–borane complexes containing different alkyl groups, including bulky groups, can be obtained by the addition of different Grignard reagents to benzothiadiphosphole **1** followed by direct complexation with BH~3~**·**THF. Treatment of the resul