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Efficient One-Pot Synthesis of Secondary Cyclic Phosphanes with Easy Regeneration of the Phosphorus-Donor Reagent Used

โœ Scribed by Graziano Baccolini; Carla Boga; Matteo Galeotti


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
93 KB
Volume
116
Category
Article
ISSN
0044-8249

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General and Efficient One-Pot Synthesis
โœ Graziano Baccolini; Carla Boga; Marzia Mazzacurati ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 135 KB

## Abstract Tertiary symmetric and asymmetric phosphaneโ€“borane complexes containing different alkyl groups, including bulky groups, can be obtained by the addition of different Grignard reagents to benzothiadiphosphole **1** followed by direct complexation with BH~3~**ยท**THF. Treatment of the resul