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Efficient Mo(VI)-Catalyzed Hydration of Nitrile with Acetaldoxime

โœ Scribed by Ma, Xiaoyun; He, Ying; Lu, Ming

Book ID
121434410
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
220 KB
Volume
44
Category
Article
ISSN
0039-7911

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An efficient Pd-catalyzed hydration of n
An efficient Pd-catalyzed hydration of nitrile with acetaldoxime
โœ Eun Sun Kim; Hoo Sook Kim; Jae Nyoung Kim ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 516 KB

An efficient palladium-catalyzed protocol for the hydration of nitrile to amide with acetaldoxime has been developed. A plausible mechanism was suggested involving the first Pd(II)-catalyzed nitrile-oxime coupling and the following disruption of the intermediate into amide and acetonitrile in a conc