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ChemInform Abstract: Copper(II)-Catalyzed Hydration of Nitriles with the Aid of Acetaldoxime.

โœ Scribed by Xiao-Yun Ma; Ying He; Yu-Lin Hu; Ming Lu

Book ID
112044186
Publisher
John Wiley and Sons
Year
2012
Weight
30 KB
Volume
43
Category
Article
ISSN
0931-7597

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An efficient Pd-catalyzed hydration of n
An efficient Pd-catalyzed hydration of nitrile with acetaldoxime
โœ Eun Sun Kim; Hoo Sook Kim; Jae Nyoung Kim ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 516 KB

An efficient palladium-catalyzed protocol for the hydration of nitrile to amide with acetaldoxime has been developed. A plausible mechanism was suggested involving the first Pd(II)-catalyzed nitrile-oxime coupling and the following disruption of the intermediate into amide and acetonitrile in a conc