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Efficient Epoxidation of Electron-Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2]3−

✍ Scribed by Dr. Keigo Kamata; Kosei Sugahara; Kazuhiro Yonehara; Ryo Ishimoto; Prof. Dr. Noritaka Mizuno

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
513 KB
Volume
17
Category
Article
ISSN
0947-6539

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G (m-OH) 2 ] 3À has been used as a catalyst in the chemoselective oxidation of various kinds of electron-deficient alkenes, with acetate, ether, carbonyl, and chloro groups at the allylic positions, to give the corresponding epoxides in high yields with only an equimolar amount of H 2 O 2 . Even acr

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