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ChemInform Abstract: Efficient Epoxidation of Electron-Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2] 3-.

✍ Scribed by Keigo Kamata; Kosei Sugahara; Kazuhiro Yonehara; Ryo Ishimoto; Noritaka Mizuno

Publisher
John Wiley and Sons
Year
2011
Weight
33 KB
Volume
42
Category
Article
ISSN
0931-7597

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G (m-OH) 2 ] 3À has been used as a catalyst in the chemoselective oxidation of various kinds of electron-deficient alkenes, with acetate, ether, carbonyl, and chloro groups at the allylic positions, to give the corresponding epoxides in high yields with only an equimolar amount of H 2 O 2 . Even acr

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