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Efficient Carbonylation Reactions in Phosphonium Salt Ionic Liquids: Anionic Effects

✍ Scribed by McNulty, James; Nair, Jerald J.; Robertson, Al

Book ID: 121662086
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 70 KB
Volume: 9
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol702081g

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## Abstract The Pd‐mediated Buchwald–Hartwig amination reaction of aryl halides in a phosphonium salt ionic liquid consisting of a trihexyl(tetradecyl)phosphonium cation with a range of anions has been investigated. A pronounced anionic effect was uncovered with the reaction proceeding readily with