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ChemInform Abstract: Efficient Carbonylation Reactions in Phosphonium Salt Ionic Liquids: Anionic Effects.

✍ Scribed by James McNulty; Jerald J. Nair; Al Robertson


Publisher
John Wiley and Sons
Year
2008
Weight
37 KB
Volume
39
Category
Article
ISSN
0931-7597

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A Pronounced Anionic Effect in the Pd-Ca
✍ James McNulty; Sreedhar Cheekoori; Timothy P. Bender; Jennifer A. Coggan πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 107 KB

## Abstract The Pd‐mediated Buchwald–Hartwig amination reaction of aryl halides in a phosphonium salt ionic liquid consisting of a trihexyl(tetradecyl)phosphonium cation with a range of anions has been investigated. A pronounced anionic effect was uncovered with the reaction proceeding readily with