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Efficient Asymmetric Oxidation of Sulfides and Kinetic Resolution of Sulfoxides Catalyzed by a Vanadium−Salan System

✍ Scribed by Sun, Jiangtao; Zhu, Chengjian; Dai, Zhenya; Yang, Minghua; Pan, Yi; Hu, Hongwen

Book ID
120585980
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
187 KB
Volume
69
Category
Article
ISSN
0022-3263

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Asymmetric Synthesis of Aryl Benzyl Sulf
Asymmetric Synthesis of Aryl Benzyl Sulfoxides by Vanadium-Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution in Sulfoxide Oxidation
✍ Pádraig Kelly; Simon E. Lawrence; Anita R. Maguire 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB 👁 1 views

## Abstract Enantioselective vanadium‐catalysed oxidation of aryl benzyl sulfides using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90 % __ee__), albeit with an associat