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Titanium-Salan-Catalyzed Asymmetric Oxidation of Sulfides and Kinetic Resolution of Sulfoxides with H2O2 as the Oxidant

✍ Scribed by Konstantin P. Bryliakov; Evgenii P. Talsi

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
244 KB
Volume
2008
Category
Article
ISSN
1434-193X

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Asymmetric oxidation of sulfides with H2
Asymmetric oxidation of sulfides with H2O2 catalyzed by titanium complexes with aminoalcohol derived Schiff bases
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Sulfoxidation catalysts generated in situ from titanium(IV) isopropoxide and enantiopure Schiff bases promote the enantioselective oxidation of alkyl aryl sulfides to the corresponding sulfoxides at low catalyst loadings (<1 mol%), 30% aqueous hydrogen peroxide being the terminal oxidant. Upon scree