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Vanadium-Catalyzed Enantioselective Sulfoxidation and Concomitant, Highly Efficient Kinetic Resolution Provide High Enantioselectivity and Acceptable Yields of Sulfoxides

✍ Scribed by Qingle Zeng; Heqing Wang; Tongjian Wang; Yimin Cai; Wen Weng; Yufen Zhao


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
77 KB
Volume
347
Category
Article
ISSN
1615-4150

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Asymmetric Synthesis of Aryl Benzyl Sulf
✍ PΓ‘draig Kelly; Simon E. Lawrence; Anita R. Maguire πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 171 KB πŸ‘ 1 views

## Abstract Enantioselective vanadium‐catalysed oxidation of aryl benzyl sulfides using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90 % __ee__), albeit with an associat