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Efficient and Selective Halogenation of Allylic and Benzylic Alcohols under Mild Conditions

✍ Scribed by Babasaheb P. Bandgar; Sampada V. Bettigeri

Publisher: Springer Vienna
Year: 2004
Tongue: English
Weight: 58 KB
Volume: 135
Category: Article
ISSN: 0026-9247
DOI: 10.1007/s00706-004-0212-8

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## Abstract A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using __in situ__ generated iron chloride complexes [Fe(**L3**)~2~Cl~n~] [n=0–1, **L3** =6‐(__N__‐phenylbenzimidazoyl)‐2‐pyridinecarboxylic acid], aldehydes and keto