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A method for selective conversion of allylic and benzylic alcohols to halides under neutral conditions

โœ Scribed by E.J. Corey; C.U. Kim; Makoto Takeda


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
211 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Reagents which are sufficiently selective to distinguish between functional groups of the same class are exceedingly valuable in syntheses involving multlfunctlonal molecules, since they permit operations


๐Ÿ“œ SIMILAR VOLUMES


Allyl ethyl carbonate/palladium (0), a n
โœ R. Lakhmiri; P. Lhoste; D. Sinou ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Alcohols are converted in a one-step procedure into ally1 ethers under neutral conditions, using ally1 ethyl carbonate in the presence of a catalytic amount of palladium (0). Anomeric hydroxyls are selectively allylated in the presence of other hydroxyl groups. Ally1 groups have been found to be of