𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Efficient 1,2-Asymmetric Induction in Radical Reactions: Stereoselective Radical Addition to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes

✍ Scribed by Ogura, Katsuyuki; Kayano, Akio; Sumitani, Naoko; Akazome, Motohiro; Fujita, Makoto

Book ID
126166456
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
585 KB
Volume
60
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Efficient 1,2-Asymm
ChemInform Abstract: Efficient 1,2-Asymmetric Induction in Radical Reactions: Addition of Acyl Radicals to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes and Their Acetates.
✍ Katsuyuki Ogura; Takayuki Arai; Akio Kayano; Motohiro Akazome πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

Efficient 1,2-Asymmetric Induction in Radical Reactions: Addition of Acyl Radicals to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1alkenes and Their Acetates. -Sensitized irradiation of aldehydes (II) generates acyl radicals which add to the functionalized alkenes (I). Desulfurization with Raney-N

Highly stereoselective radical addition
Highly stereoselective radical addition to 3-hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes and its application to the preparation of optically active compounds
✍ Akio Kayano; Motohiro Akazome; Makoto Fujita; Katsuyuki Ogura πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 946 KB

Ettlcient 1.2-asymmetric induction was realized in the addition ot a l-hydroxyalkyl radical (R2(7-OIt) to 3-hydroxy-l-(methylthio)-l-Cp-tolylsulfonyl)-l-alkenes and their acetates (1): Irradiationot l and benzophenone in an 'alcohol (R2CHOH) gave an adduct (2) with a high syn selectivity. Optically