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ChemInform Abstract: Efficient 1,2-Asymmetric Induction in Radical Reactions: Addition of Acyl Radicals to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes and Their Acetates.

✍ Scribed by Katsuyuki Ogura; Takayuki Arai; Akio Kayano; Motohiro Akazome

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199926038

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✦ Synopsis

Efficient 1,2-Asymmetric Induction in Radical Reactions: Addition of Acyl Radicals to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1alkenes and Their Acetates.

-Sensitized irradiation of aldehydes (II) generates acyl radicals which add to the functionalized alkenes (I). Desulfurization with Raney-Ni provides the products (IV) with high syn-selectivity. -

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v