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1,3-Stereoinduction in Radical Reactions: Radical Additions to Dialkyl 2-Alkyl-4-methyleneglutarates

✍ Scribed by Hayen, Ahlke; Koch, Rainer; Saak, Wolfgang; Haase, Detlef; Metzger, Jürgen O.


Book ID
126295031
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
138 KB
Volume
122
Category
Article
ISSN
0002-7863

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Addition of radicals to quinones—III. ES
✍ T.L. Simándi; A. Rockenbauer; F. Tüdős 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 365 KB

Reactions between 2,6-dialkyl-l,4-benzoquinones and various free radicals have been studied by ESR spectroscopy. The stable intermediates were identified on the basis of their spectra. It has been established that cyanoisopropyl, polystyryl and poly-(ct-methylstyryl) radicals attack at the oxygen at