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Efficiency of O2(1Σg+) formation by O(1D) + O2

✍ Scribed by D.R. Snelling; M. Gauthier

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 364 KB
Volume: 9
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)85044-3

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✦ Synopsis

The efficiency of formation of 0 (lC*) by energy transfer between O(lD) and 0, has been measured relative to the efficiency of O&J f or 18 t a ion by photol~sis of ozone at 2587 A. ThG "Iwo singlet states of molecular oxygen were formed in a tlow system and their relative concentrations determiaed wit? a caffbrated detection system by measuring their emission at 7620 A and 1.27 /.I. The results show t??t if the cfficiendy of 02(lA,) formation by 02 photolysis is unity then the 1Zg state of 02 is produced in more than (85* 15) 5$ of the collisions deactivating O(lD). This determi~tion IS compared with previous re-.

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