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Effects of water content on the enantioselectivity of α-chymotrypsin catalysis in organic media

✍ Scribed by Katsuhiro Kawashiro; Hideki Sugahara; Sigeru Sugiyama; Hiromu Hayashi

Publisher
Springer Netherlands
Year
1995
Tongue
English
Weight
415 KB
Volume
17
Category
Article
ISSN
0141-5492

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Effect of ester moiety of substrates on enantioselectivity of protease catalysis in organic media
✍ Katsuhiro Kawashiro; Hideki Sugahara; Tomoya Tsukioka; Shigeru Sugiyama; Hiromu 📂 Article 📅 1996 🏛 Springer Netherlands 🌐 English ⚖ 417 KB

The a-chymotrypsin-catalyzed transesterification between a racemic N-trifluoroacetylphenylalanine ester and 1-propanol, was carried out in organic media. Although activation of the substrate by introducing electron-withdrawing group to the ester moiety enhanced the rate of reaction, it decreased ena