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Effects of transition-metal ions on the reduction of di-2-pyridyl ketone with sodium borohydride

✍ Scribed by Suh, Myunghyun Paik; Kwak, Chee Hun; Suh, Junghun

Book ID
127162991
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
520 KB
Volume
28
Category
Article
ISSN
0020-1669

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## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from force‐field calculations; __i.e.__ the strain difference between alcohol and ketone (Ξ” strain) and the steric hindrance towards approach of the hydride R. Models