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Reductions with Metal Hydrides. XI. Solvent Effect on the Stereochemistry of Reduction with Sodium Borohydride

✍ Scribed by Haubenstock, Howard.; Eliel, Ernest L.

Book ID
119990901
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
541 KB
Volume
84
Category
Article
ISSN
0002-7863

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Steric Effects in the Reduction of Keton
Steric Effects in the Reduction of Ketones with Sodium Borohydride
✍ Paul MΓΌller; Jean-Claude Perlberger πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 267 KB

## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from force‐field calculations; __i.e.__ the strain difference between alcohol and ketone (Ξ” strain) and the steric hindrance towards approach of the hydride R. Models