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The Stereochemical Effect of a Carboxyl Function on the Reduction of Ketones with Sodium Borohydride 1a

✍ Scribed by House, Herbert O.; Babad, Harry; Toothill, Richard B.; Noltes, Arend W.

Book ID
126445512
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
789 KB
Volume
27
Category
Article
ISSN
0022-3263

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Steric Effects in the Reduction of Keton
Steric Effects in the Reduction of Ketones with Sodium Borohydride
✍ Paul MΓΌller; Jean-Claude Perlberger πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 267 KB

## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from force‐field calculations; __i.e.__ the strain difference between alcohol and ketone (Ξ” strain) and the steric hindrance towards approach of the hydride R. Models