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Effects of substituents on combination and disproportionation of diarylketyl radicals and radical anions

โœ Scribed by Cohen, Saul G.; Ramsay, G. Caird; Stein, Nina M.; Weinstein, Sandra Y.


Book ID
121400384
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
901 KB
Volume
96
Category
Article
ISSN
0002-7863

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The disproportionation and combination o
โœ R. S. Konar ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 159 KB

Several attempts have been made to correlate the disproportionation and the combination rate constant ratio, k,/k,, of the alkyl radicals with the entropy change of the processes [ 1-31. Bradley [I] made a specific suggestion that the k,/k, ratio is a function of the entropy change of the processes