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Electron affinity and substituent effects in radical anions

✍ Scribed by A. N. Egorochkin; O. V. Kuznetsova; O. V. Novikova

Book ID
111459135
Publisher
Springer
Year
2007
Tongue
English
Weight
151 KB
Volume
77
Category
Article
ISSN
1070-3632

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Substituent effect on electron affinity,
Substituent effect on electron affinity, gas-phase basicity, and structure of monosubstituted propynyl radicals and their anions: A theoretical study
✍ Gab-Yong Lee πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 484 KB

## Abstract The substituent effect of electron‐withdrawing groups on electron affinity and gas‐phase basicity has been investigated for substituted propynl radicals and their corresponding anions. It is shown that when a hydrogen of the α‐CH~3~ group in the propynyl system is substituted by an elec