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The disproportionation and combination of alkyl radicals

✍ Scribed by R. S. Konar

Publisher: John Wiley and Sons
Year: 1970
Tongue: English
Weight: 159 KB
Volume: 2
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550020507

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✦ Synopsis

Several attempts have been made to correlate the disproportionation and the combination rate constant ratio, k,/k,, of the alkyl radicals with the entropy change of the processes [ 1-31. Bradley [I] made a specific suggestion that the k,/k, ratio is a function of the entropy change of the processes involved. Trotman-Dicken-

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