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Disproportionation reactions between alkyl and fluoroalkyl radicals. IV. Pentafluoroethyl and ethyl radicals

✍ Scribed by G. O. Pritchard; V. H. Kennedy; G. M. Heldoorn; M. L. Piasecki; K. A. Johnson; D. R. Golan

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
552 KB
Volume
19
Category
Article
ISSN
0538-8066

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✦ Synopsis

A new determination of the disproportionation/cornbination ratio for C2Fs and CZH, radicals gives a value of A(C2F,, C2H,) = 0.24 5 0.02, independent of temperature. The cross-combination ratio for the two radicals was found to increase with temperature and the significance of this is discussed in evaluating A.

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