Effects of structural changes on acidities and homolytic bond dissociation energies of the hydrogen-nitrogen bonds in amidines, carboxamides, and thiocarboxamides
โ Scribed by Bordwell, Frederick G.; Ji, Guo Zhen
- Book ID
- 115466467
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 543 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Acidities and bond dissociation energies (BDEs) of the N-H bond in two phenylsulfenylamides, PhSNHBz and PhSNH-t-Bu, and four phenylsulfenylanilides, 4-GC 6 H 4 NHSPh, where G = MeO, H, Br and CN, were measured in order to compare the effects of substituents on acidities and BDEs of N-H bonds with t
Ab initio 3CF and SCP Cl caJcuJatjons ~4th Zhe STO-3C basis set have been pcrformcd in this study of the effect of jntramolccubr hydrogen bonding on n orbital cncrgjcs and n -r I?\* transition encrgiw in ,&hydroxyacrofcin. In the hydrogen bonded C, form, the n orbital is stabWed and the n -+ s\* tnn