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Effects of solvent on the unimolecular decomposition of t-butyl peroxide

โœ Scribed by Huyser, Earl S.; VanScoy, Richard M.

Book ID
127164938
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
575 KB
Volume
33
Category
Article
ISSN
0022-3263

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Thermal decomposition of perfluoro-di-t-
Thermal decomposition of perfluoro-di-t-butyl peroxide
โœ R. Ireton; A. S. Gordon; D. C. Tardy ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 251 KB

The thermal decomposition of perfluoro-di-t-butyl peroxide has been studied for the first time. The reaction was carried out in the gas phase between 5 and 600 torr in the 10&149"C temperature region. The products consisted solely of CzFa and CFJCOCF,. The decomposition wits found to be first order