✦ LIBER ✦

Thermal decomposition of perfluoro-di-t-butyl peroxide

✍ Scribed by R. Ireton; A. S. Gordon; D. C. Tardy

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 251 KB
Volume: 9
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550090508

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✦ Synopsis

The thermal decomposition of perfluoro-di-t-butyl peroxide has been studied for the first time. The reaction was carried out in the gas phase between 5 and 600 torr in the 10&149"C temperature region. The products consisted solely of CzFa and CFJCOCF,. The decomposition wits found to be first order and homogeneous. The rate constant is given by log kdecomp (sec-I) = (16.2 rt 1.2) -(148.7 k 4.4)/2.3B1' where R is 0.008314kJ/mol . "K. These Arrhenius parameters are consistent with those determined for the decomposition of di-t-butyl peroxide.

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