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Addition reaction of tetrafluorohydrazine to perfluoro-t-butyl hypofluorite

✍ Scribed by M.S. Toy; R.S. Stringham

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 209 KB
Volume: 7
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)83999-8

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✦ Synopsis

Tetrafluorohydrazine was added to neat perfluoro-t-butyl hypofluorite, where N2F4 functions as a fluoroxy fluoronium ion acceptor, to form a white crystalline adduct (m.p. % 15O'C) in 50% yield. The product, which is soluble in hydrogen fluoride and characterized by IR, "F NMR and mass spectra, is suggested as pentafluorohydrazinium perfluoro-t-butoxide. The analytical results of the salt are described and discussed.

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