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Reaction of polyfluorinated imines with trifluoromethyltrimethylsilane. Direct synthesis of N-(perfluoro-t-butyl)amines

✍ Scribed by Viacheslav A. Petrov

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 143 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01182-5

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✦ Synopsis

The reaction of N-arylimines of hexa¯uoroacetone and CF 3 Si(CH 3 ) 3 (1) in the presence of CsF results in a 48±84% yield formation of ArN(H)C(CF 3 ) 3 . The reaction requires an equimolar amount of CsF and rapidly proceeds in solvents such as THF or monoglyme. Interaction of CF 3 NC(CF 3 ) 2 with excess of 1 leads to the formation of novel amine [(CF 3 ) 3 C] 2 NH. Stable salt of this amine is isolated in a reaction of isomeric CF 3 CF 2 NCFCF 3 with an excess of 1 in the presence of CsF. # 2000

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