Deuterium isotope effects in the decompositions of acetyl peroxide and two t-butyl peresters
β Scribed by T.W. Koenig; W.D. Brewer
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 234 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
While many quantitative studies (1) of the rates and products of the decomposition of acetyl peroxide have been
π SIMILAR VOLUMES
The thermal decomposition of di-tertiary-butyl peroxide vapor is exothermic, and, in a closed vessel, the resultant self-heating may lead to ignition. The parameters that determine the criteria for ignition are encapsulated in Frank-Kamenetskii's 6, and they include exothetrnicity and Arrhenius cons
## Abstract The proton transfer equilibrium in a series of double Schiff base derivatives of __trans__β1,2βdiaminocyclohexane in solution and the solid state was studied by means of ^15^N NMR spectroscopy and analysis of the deuterium isotope effect on the chemical shifts Ξ^15^N(D). The presence of