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Deuterium isotope effects in the thermal decomposition of β hydroxy ketones and β-hydroxy esters

✍ Scribed by J. Quijano; M.M. Rodríguez; M. del S. Yepes; L.H. Gallego

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
188 KB
Volume
28
Category
Article
ISSN
0040-4039

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## Abstract The pyrolysis kinetics of primary, secondary, and tertiary β‐hydroxy ketones have been studied in static seasoned vessels over the pressure range of 21–152 torr and the temperature range of 190°–260°C. These eliminations are homogeneous, unimolecular, and follow a first‐order rate law.