Rate constants for the gas-phase reactions of NO3 radicals with a series of cycloalkenes have been determined at 298 2 2 K, using a relative rate technique. Using an equilibrium constant for the NOz + NO3 F? N2D5 reactions of 3.4 x lo-" cm3 molecule-', the following rate constants (in units of cm3 m
Effects of ring strain on gas-phase rate constants. 2. OH radical reactions with cycloalkenes
โ Scribed by Roger Atkinson; Sara M. Aschmann; William P. L. Carter
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 768 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0538-8066
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๐ SIMILAR VOLUMES
Rate constants for the gas-phase reactions of 0 3 with a series of cycloalkenes and with cis-2-butene have been determined at 297 f 1 K. The rate constants obtained were (in units of cm3/molecule-s): cis-2-butene, 1.38 f 0.16; cyclopentene, 2.75 f 0.33; cyclohexene, 1.04 f 0.14; cycloheptene, 3.19 f
Relative rate constants for the gas-phase reactions of OH radicals with a series of bi-and tricyclic alkanes have been determined at 299 f 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 X cm3/mole
Using a relative rate method, rate constants have been measured for the gasphase reactions of the OH radical with the dibasic esters dimethyl succinate The rate constants ob-298 ฯฎ 3 K. tained were (in units of ): dimethyl succinate, dimethyl 10 cm molecule s 1.4 ฯฎ 0.6; glutarate, and dimethyl adip
## Abstract Using a relative rate method, rate constants for the gasโphase reactions of the OH radical with __trans__โpinane [(1R, 2R)โ2, 6, 6โtrimethylbicyclo[3.1.1]heptane], tricyclene (1, 7, 7โtrimethyltricyclo[2.2.1.0^2, 6^]heptane), and quadricyclane (quadricyclo[2.2.1.0^2, 6^.0^3, 5^]heptane)