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Effects of licand environment on nucleophile addition to cyclohexadienyliron cations.

✍ Scribed by Anthony J. Pearson; Jaeyon Yoon


Book ID
108382562
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
201 KB
Volume
26
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Observations on regioselectivity during
✍ Anthony J. Pearson; Manoj Babu πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 215 KB

Addition of carbon nucleophiles, such as phenylmagnesium bromide, to isoprene-Mo(CO)2Tp (Tp = hydridotris(l-pyrazolyl)borato), can proceed with excellent regiocontrol, predominantly at the diene terminus remote from the 2-methyl substituent. In contrast to the corresponding cyclopentadienyl complex,