Reactivity of (pentadienyl)iron(1+) cations: Effect of peripheral ligands on the regioselectivity of nucleophilic addition
β Scribed by William A. Donaldson; Lewei Shang
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 143 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Addition of carbon nucleophiles, such as phenylmagnesium bromide, to isoprene-Mo(CO)2Tp (Tp = hydridotris(l-pyrazolyl)borato), can proceed with excellent regiocontrol, predominantly at the diene terminus remote from the 2-methyl substituent. In contrast to the corresponding cyclopentadienyl complex,
## Abstract The effects of the oxidation state, the ligand, and the solvent on structures and energetics of cationic iron complexes are investigated by means of electrosprayβionization mass spectrometry. Insights into the potentialβenergy surfaces of FeX^+^, FeX~2~^+^, and XFe(OCH~3~)^+^ ions (X =