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Effects of isotopic substitution on the chemiluminescence spectra obtained during the reaction of F2 with CS2

✍ Scribed by Robert J. Glinski; C.Douglas Taylor

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
146 KB
Volume
155
Category
Article
ISSN
0009-2614

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✦ Synopsis

Emission spectra have been obtained during the gas-phase reaction of F, with CSa on substitution with carbon-13 and sulfur-34 in effort to ascertain the identity of the emitter. Absence of any measurable shift in the vibronic bands on substitution with carbon-13 suggests that carbon is not present in the emitting molecule and that the previous assignment should be discarded. The measured vibrational frequencies and their shifts on isotopic substitution with sulfur-34 are nearly identical to those that have been reported previously by other workers for the ground electronic state of SF*.

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