The product polarixation in the beam-gas chemiluminescent reactions Ca( 'Pi) + RI-CaI\*+R for different initial Ca eleo tronic orbital alignments are both probed experimentally and calculated with the DIP extension of the DIPR model (the direct interaction with product repulsion (DIPR) model, with p
Dependence of product alignment on product vibration for the Ca + F2 chemiluminescent reaction
โ Scribed by M.G. Prisant; C.T. Rettner; R.N. Zare
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 264 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The product polarization for the beam-gas chemiluminescent reaction ,Ca( 1 So) + F2 ~ CaF(B 2 E+) + F is found to be vary by more than a factor of two over the B-X band system. This reveals a strong dependence of CaF(B) state alignment on vibrational level.
๐ SIMILAR VOLUMES
The inlrared emission of l\*(\*P1& aloms at 1315 pm has been observed m a fast-flow reactor from the renct~on of F atoms with iodine mokules. F atoms were produced either in an electronic discharge by dl-ation of a Iluorinakd compound or tn a mmbustor from rhc reaction of CA-F2 and Dz with helium di
Dcparrrrwnr uf Cixrmistr> . Statr\_ford Unil ersirj . Smnford. Calijornia 9J305. US.4 Kecrnsd 15 \_aprrl 1963: in find1 form 31 May 19S3 The effect of reagent rotation on the product vibrstional state distribution is reported for the reaction Ca('S) + W(S lx+." = 1.J) -Cal'(S"+, u'.J') + II( An infr