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Effects of Fluorine on the Structures and Energetics of the Propynyl and Propargyl Radicals and Their Anions

✍ Scribed by Sreeruttun, Raj K.; Ramasami, Ponnadurai; Wannere, Chaitanya S.; Paul, Ankan; Schleyer, Paul v. R.; Schaefer, Henry F.


Book ID
127259346
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
520 KB
Volume
70
Category
Article
ISSN
0022-3263

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## Abstract The substituent effect of electron‐withdrawing groups on electron affinity and gas‐phase basicity has been investigated for substituted propynl radicals and their corresponding anions. It is shown that when a hydrogen of the α‐CH~3~ group in the propynyl system is substituted by an elec