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Structures and energies of the radicals and anions generated from chlorpyrifos

✍ Scribed by Yi Zhang; Chang-Zhong Liu; Xiao-Jun Li; Zi-Liang Wang; Hai-Tang Zhang; Zhi-Guo Miao


Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
483 KB
Volume
16
Category
Article
ISSN
1610-2940

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Acid chlorides react with Sm12 to give a-diketones.Various experiments show that theinitially formed acyl radical is rapidly transformed into an acyl anion which is thus generated byquite an unusual route. This species acylates acid chlorides, aldehydes and ketones in situ to give a-diketones and a-

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✍ Robert I. McNeil; Ffrancon Williams; Moon B. Yim πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 563 KB

EPR spectra attributable to the halogenotrifluoroethylene radical anions have been generated by electron attachment in solid soiutions at Iow temperatures. The spin density distrtbution in these rdids strongly suzeststhat the unpaired electron occupies a (I\* orbital. a conclusion which is supported