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Photochemical generation of anion-radicals of bacteriochlorophyll and bacteriopheophytin

✍ Scribed by V. M. Voznyak; V. A. Kim; V. B. Evstigneev

Publisher
Springer US
Year
1975
Tongue
English
Weight
328 KB
Volume
23
Category
Article
ISSN
0021-9037

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## Abstract Photolysis of a series of __E__ or __Z__ stereoisomeric α‐R‐substituted bromostyrenes (R = CH~3~, F or CN) in methanol yields __E__ and/or __Z__ stereoisomeric styrenes, which stem from the corresponding vinyl radicals. The results show that the α‐Me vinyl radical is a rapidly equilibra