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Energetics and Structures of Adamantane and the 1- and 2-Adamantyl Radicals, Cations, and Anions

โœ Scribed by Yan, Ge; Brinkmann, Nicole R.; Schaefer, Henry F.


Book ID
120996023
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
122 KB
Volume
107
Category
Article
ISSN
1089-5639

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Towards persistent cyclobutadiene radica
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The persistence of alkyl substituted cyclobutadiene radical cations strongly depends on the method of generation and the size of the alkyl substituents used. Hindered rotation, the consequence of bulky substituents, is observed in the title compounds. Cyclobutadiene radical cations are transient spe